In an effort to improve volatile organic compound (VOC) detection, a collaboration of Japanese researchers from Kumamoto University, Fukuoka Industrial Technology Centre and Tohoku University recently set out to improve sensor sensitivity by modifying the particle and pore sizes of Tin-dioxide (SnO2) nanocrystals on sensing film.
They knew that particle size was a determining factor in sensor response, so they formulated a method to synthesise SnO2 particles of different sizes and pore distribution patterns, and ran an analysis to determine optimal sensor film particle morphology for various gasses.
Using a hydrothermal method, the researchers synthesised SnO2 nanocubes and nanorods, and created gas-sensing films of various pore and particle sizes. Nanocrystals created in this experiment were developed using organic molecules in an acidic solution, which is a major difference from previous experiments that used cations in an alkaline solution. Films made from nanocubes had very small pores, less than 10nm, whereas films made with nanorods were distinctly porous with pore sizes larger than10 nm. Palladium (Pd)-loaded SnO2 nanocrystals were also synthesised to test the idea that Pd-loading would improve sensor response by changing pore sizes. The gasses used to test the new sensors were hydrogen (200ppm), ethanol (100ppm), and acetone (100ppm). Sensor response (S) was calculated using a ratio of electrical resistance produced in air (Ra) to the resistance produced by the testing gas (Rg) (S=Ra/Rg).
The research team found that the sensors had the best response when using long (500 nm) nanorods at a temperature of approximately 250°C, except for the H2 sensor, which responded best at a temperature of 300°C with nanocubes. Furthermore, Pd-loaded sensors had an improved response at 250°C with long nanorods being the best performing nanocrystal morphology for each of the gasses tested. “Our experiments show that the TiO2 nanocrystal sensors with larger pore sizes gave the best sensor responses. In particular, we found ultra-high sensitivity (increasing by five orders of magnitude) in the devices with largest pore size, the long nanorod sensors,” said Professor Tetsuya Kida of Kumamoto University. “This tells us that is beneficial to have precise control over the manufacturing methods of these types of sensors.”
One drawback of the new sensors is their relatively long recovery time. Even though the response time was swift, between 15 and 21 seconds, the recovery time fell between 157 to 230 minutes. This was thought to be caused by reaction byproducts remaining on the surface of the sensor film. Additionally, experimental and simulation results for ethanol showed that sensors with pore sizes over 80nm are prone to saturate. However, it is likely that this can be overcome by pore size optimization and controlling the sensor film electrical resistance.